Syntheses, Structures and Solid-State Properties of MMX Mixed-Valence Chains, [NiII/III2(RCS2)4I]∞ (R = Et, n-Pr and n-Bu): Evidence of a Spin-Peierls Transition

Author:

Mitsumi Minoru1,Yoshida Yuji1,Kohyama Akihisa1,Kitagawa Yasutaka2,Ozawa Yoshiki1,Kobayashi Mototada1,Toriumi Koshiro1,Tadokoro Makoto3,Ikeda Naoshi4,Okumura Mitsutaka2,Kurmoo Mohamedally5

Affiliation:

1. Department of Material Science, Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan

2. Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka 560-0043, Japan

3. Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan

4. Japan Synchrotron Radiation Research Institute,1-1 Kouto, Mikazuki-cho, Sayo-gun, Hyogo 679-5198, Japan

5. Laboratoire de Chimie de Coordination Organique, CNRS-UMR 7140, Université de Strasbourg, 4 rue Blaise Pascal, F-67000 Strasbourg, France

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Reference83 articles.

1. bDay, P.InChemistry and Physics of One-Dimensional Metals;Keller, H. J., Ed.Plenum Press:New York, 1977; NATO ASI Ser., Ser. B, Vol.25, pp197−223.

2. cSoos, Z. G. and Keller, H. J.InChemistry and Physics of One-Dimensional Metals;Keller, H. J., Ed.Plenum Press:New York, 1977; NATO ASI Ser., Ser. B, Vol.25, pp391−412.

3. Nyholm Lecture. Synthesis, structure, and spectroscopy of metal–metal dimers, linear chains, and dimer chains

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