P−C Bond Cleavage by a Heterobimetallic Polyhydrido Complex, (C5Me5)Ru(μ-H)3Ir(C5Me5). Structure Determination and Fluxional Behavior of a Bridging Phosphido Complex, (C5Me5)Ru(μ-PPh2)(μ-H)(μ-η1:η2-C6H5)Ir(C5Me5)
Author:
Affiliation:
1. Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552, Japan
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om049162k
Reference23 articles.
1. Synthesis, Characterization, and Structure Determination of the Heterobimetallic Polyhydride Complexes (C5Me5)Ru(μ-H)3MH3(C5Me5) (M = Mo, W) Containing Group VI and Group VIII Metals
2. Heterobimetallic Polyhydride Complex Containing Ruthenium and Iridium. Synthesis and Site-Selectivity in the Reaction with Unsaturated Hydrocarbons
3. Phosphorus-carbon bond activation of triphenylphosphine. Formation of a dinuclear .mu.-.eta.2:.eta.2-benzene complex of ruthenium
4. Phase-transfer-catalyzed cleavage of carbon-hydrogen and carbon-phosphorus bonds in PPh3 by an iridium complex. Synthesis and molecular structure of [Ir2(C5Me5)2(.mu.-H)(.mu.-PPh2)(.mu.-C6H4)]
5. Stereochemical consequences of deprotonation of the bent molybdenum-hydrogen-molybdenum bond in Mo2(.eta.5-C5H5)2(CO)4(.mu.-H)(.mu.-PMe2)
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