Experimental and Theoretical Studies of Bonding and Oxidative Addition of Germanes and Silanes, EH4-nPhn (E = Si, Ge; n = 0−3), to Mo(CO)(diphosphine)2. The First Structurally Characterized Germane σ Complex-Reference-Cited by-同舟云学术

Experimental and Theoretical Studies of Bonding and Oxidative Addition of Germanes and Silanes, EH4-nPhn (E = Si, Ge; n = 0−3), to Mo(CO)(diphosphine)2. The First Structurally Characterized Germane σ Complex

Published:2003-11-06 Issue:25 Volume:22 Page:5307-5323
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Vincent Jean L.¹,Luo Steven¹,Scott Brian L.¹,Butcher Ray¹,Unkefer Clifford J.¹,Burns Carol J.¹,Kubas Gregory J.¹,Lledós Agusti¹,Maseras Feliu¹,Tomàs Jaume¹

Affiliation:

1. Chemistry Division, Los Alamos National Laboratory, MS J514, Los Alamos, New Mexico 87545, and Departament de Química, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om030569j

Reference64 articles.

1. (a)Metal Dihydrogen andσ-Bond Complexes; Kubas, G. J.; Kluwer Academic/Plenum Publishers: New York, 2001.

2. Metal–dihydrogen and σ-bond coordination: the consummate extension of the Dewar–Chatt–Duncanson model for metal–olefin π bonding

3. Transition Metal Complexation ofσ Bonds

4. η2 Coordination of Si–H σ Bonds to Transition Metals

5. Reactions of Hydrosilanes with Transition-Metal Complexes: Formation of Stable Transition-Metal Silyl Compounds

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