trans-RuH(η-BH4)(binap)(1,2-diamine): A Catalyst for Asymmetric Hydrogenation of Simple Ketones under Base-Free Conditions
Author:
Affiliation:
1. Nagoya University, Department of Chemistry and Research Center for Materials Science, Chikusa, Nagoya 464-8602, Japan, and Tohoku University, Instrumental Analysis Center for Chemistry, Graduate School of Science, Aoba, Sendai 980-8578, Japan
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja026136%2B
Reference13 articles.
1. trans-[RuCl2(phosphane)2(1,2-diamine)] and Chiraltrans-[RuCl2(diphosphane)(1,2-diamine)]: Shelf-Stable Precatalysts for the Rapid, Productive, and Stereoselective Hydrogenation of Ketones
2. Asymmetric Catalysis by Architectural and Functional Molecular Engineering: Practical Chemo- and Stereoselective Hydrogenation of Ketones
3. Preparation of trans-RuH(η1-BH4)L (L = Me6[15]aneS4, Me8[16]aneS4) and oxidation in alcohols to give trans-{Ru(OR)2(anti-Me8[16]aneS4)}+ R = Me, Et). Crystal structures of the hydrido and ethoxo complexes of Me8[16]aneS4
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