A Change from Kinetic to Thermodynamic Control Enables trans-Selective Stereochemical Editing of Vicinal Diols
Author:
Affiliation:
1. Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States
Funder
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.1c11902
Reference61 articles.
1. Enantioselective formation of quaternary carbon stereocenters in natural product synthesis: a recent update
2. Catalytic Enantioselective Olefin Metathesis in Natural Product Synthesis. Chiral Metal-Based Complexes that Deliver High Enantioselectivity and More
3. The Asymmetric Intramolecular Heck Reaction in Natural Product Total Synthesis
4. Synthesis of rare sugar isomers through site-selective epimerization
5. Light - driven deracemization enabled by excited - state electron transfer
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