Reductive Reactivity of the Organolanthanide Hydrides, [(C5Me5)2LnH]x, Leads to ansa-Allyl Cyclopentadienyl (η5-C5Me4CH2−C5Me4CH2-η3)2- and Trianionic Cyclooctatetraenyl (C8H7)3- Ligands-Reference-Cited by-同舟云学术

Reductive Reactivity of the Organolanthanide Hydrides, [(C5Me5)2LnH]x, Leads to ansa-Allyl Cyclopentadienyl (η5-C5Me4CH2−C5Me4CH2-η3)2- and Trianionic Cyclooctatetraenyl (C8H7)3- Ligands

Published:2008-06-10 Issue:26 Volume:130 Page:8555-8563
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Evans William J.¹,Schmiege Benjamin M.¹,Lorenz Sara E.¹,Miller Kevin A.¹,Champagne Timothy M.¹,Ziller Joseph W.¹,DiPasquale Antonio G.¹,Rheingold Arnold L.¹

Affiliation:

1. Department of Chemistry, University of California, Irvine, California 92697-2025, and Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, MC 0358 La Jolla, California 92093-0358

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja8011726

Reference65 articles.

1. Synthesis and properties of bis(pentamethylcyclopentadienyl) actinide hydrocarbyls and hydrides. A new class of highly reactive f-element organometallic compounds

2. Actinide Hydride Complexes as Multielectron Reductants: Analogous Reduction Chemistry from [(C5Me5)2UH]2, [(C5Me5)2UH2]2, and [(C5Me5)2ThH2]2

3. Synthesis, Structure, and Reactions of Hydride, Borohydride, and Aluminohydride Compounds of the f-Elements

4. Highly reactive organolanthanides. Systematic routes to and olefin chemistry of early and late bis(pentamethylcyclopentadienyl) 4f hydrocarbyl and hydride complexes

5. A kinetic, mechanistic, and molecular mechanics investigation of olefin insertion into organoactinide-hydride bonds. Metal, olefin, ancillary ligand, and diastereoselection effects

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