Copper-Catalyst-Controlled Site-Selective Allenylation of Ketones and Aldehydes with Propargyl Boronates
Author:
Affiliation:
1. Chemical Development, Boehringer-Ingelheim Pharmaceuticals Inc., 900 Ridgebury Road, P.O. Box 368, Ridgefield, Connecticut 06877-0368, United States
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol400124f
Reference27 articles.
1. Two Approaches to Diverting the Course of a Free-Radical Cyclization: Application of Cyclopropylcarbinyl Radical Fragmentations and Allenes as Radical Acceptors
2. 2-(Acetoxymethyl)buta-2,3-dienoate, a Versatile 1,4-Biselectrophile for Phosphine-Catalyzed (4 + n) Annulations with 1,n-Bisnucleophiles (n = 1, 2)
3. B-(.gamma.-(Trimethylsilyl)propargyl)diisopinocampheylborane: A New, Highly Efficient Reagent for the Enantioselective Propargylboration of Aldehydes. Synthesis of Trimethylsilyl-Substituted and Parent .alpha.-Allenic Alcohols in High Optical Purity
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