Synthesis of Homoallylic Chiral Tertiary Alcohols via Chelation-Controlled Diastereoselective Nucleophilic Addition on α-Alkoxyketones:  Application for the Synthesis of the C1−C11 Subunit of 8-epi-Fostriecin

Author:

Ramachandran P. Veeraraghavan1,Liu Haipeng1,Ram Reddy M. Venkat1,Brown Herbert C.1

Affiliation:

1. Herbert C. Brown Center for Borane Research, 560 Oval Drive, Department of Chemistry, Purdue University, West Lafayette, Indiana 47907-2084

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference37 articles.

1. Acyclic stereocontrol via allylic organometallic compounds

2. Selective reactions using allylic metals

3. α-Chiral allylboronates: reagents for asymmetric synthesis

4. (b) Roush, W. R. ACS Symposium Series 386; American Chemical Society:  Washington, DC, 1989; p 242.

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