A Becke3LYP/6-31G* Study of the Cope Rearrangements of Substituted 1,5-Hexadienes Provides Computational Evidence for a Chameleonic Transition State-Reference-Cited by-同舟云学术

A Becke3LYP/6-31G* Study of the Cope Rearrangements of Substituted 1,5-Hexadienes Provides Computational Evidence for a Chameleonic Transition State

Published:1999-10-30 Issue:45 Volume:121 Page:10529-10537
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Hrovat David A.¹,Beno Brett R.¹,Lange Holger¹,Yoo Hi-Young¹,Houk K. N.¹,Borden Weston Thatcher¹

Affiliation:

1. Contribution from the Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569 and the Department of Chemistry, Box 351700, University of Washington, Seattle, Washington 98195-1700

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja990476m

Reference38 articles.

1. Die Bildungsenthalpie des Allyl- und Methallyl-Radikals

2. Impact of upwardly revised Hf0 of primary, secondary, and tertiary radicals on mechanistic constructs in thermal reorganizations

3. Kinetics of the cope rearrangement of 1,1-dideuteriohexa-1,5-diene

4. A study of the mechanism of the Cope rearrangement

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