Palladium Catalyzed Regioselective β-Acetonation−α-Allylation of Activated Olefins in One Shot

Author:

Shim Jae-Goo1,Nakamura Hiroyuki1,Yamamoto Yoshinori1

Affiliation:

1. Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980−8578, Japan

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Reference38 articles.

1. For general reviews:  (a) Trost, B. M.; Verhoeven, T. R.ComprehensiveOrganometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon Press:  New York, 1982; Vol. 8, p 799. (b) Heck, R. F.PalladiumReagents in Organic Synthesis, Academic Press:  London, 1987; p 117. (c) Tsuji, J.Palladium Reagents and Catalysts, John Wiley & Sons:  Chichester, 1995; p 290. (d) Trost, B. M.Angew. Chem.1995,107, 285;Angew. Chem.Int. Ed. Engl.1995,34, 259.

2. Neutral alkylations via palladium(0) catalysis

3. Allylic carbonates. Efficient allylating agents of carbonucleophiles in palladium-catalyzed reactions under neutral conditions

4. Measurement of the secondary hydrogen-deuterium isotope effect in atom transfer reactions of the 1,1-dideuterioallyl radical

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