Synthesis of Novel Mixed Metal Cluster Complexes of Osmium and Mercury: Formation of the Wheel-Shaped Cluster Complexes Os6(μ6-Hg)(μ-PR2)2(CO)20 (R = Ph, i-Bu)-Reference-Cited by-同舟云学术

Synthesis of Novel Mixed Metal Cluster Complexes of Osmium and Mercury: Formation of the Wheel-Shaped Cluster Complexes Os6(μ6-Hg)(μ-PR2)2(CO)20 (R = Ph, i-Bu)

Published:2002-04-02 Issue:9 Volume:21 Page:1925-1932
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Egold Hans¹,Schraa Markus¹,Flörke Ulrich¹,Partyka Janusch¹

Affiliation:

1. Anorganische und Analytische Chemie der Universität Paderborn, Fachbereich 13, Chemie und Chemietechnik, Warburgerstr. 100, D-33098 Paderborn, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om0110585

Reference41 articles.

1. Synthesis and crystal structure of mercury-bridged transition-metal clusters: Hg[Ru3(CO)9(C2-tert-Bu)]2 and [(C2-tert-Bu)Ru3(CO)9HgMo(.eta.-C5H5)(CO)3]

2. Mercury-bridged, nitrosyl substituted, triruthenium carbonyl clusters: Synthesis and x-ray crystal structure of [Ru3(NO)(CO)10]2Hg

3. Reactivity and ligand dynamics of a skeletally chiral metal cluster: [(.mu.3-.eta.2-C2Bu-tert)(CO)9Ru3]2(.mu.4-Hg)

4. Mercury-bridged transition-metal clusters. 5. Synthesis and structure of (.mu.3-.eta.2-C2-tert-Bu)(CO)9M3(.mu.3-Hg)M' [M = Ru, Os; M' = Fe(.eta.5-C5H5)(CO)2, Ru(.eta.5-C5H5)(CO)2, Mo(.eta.5-C5H5)(CO)3, Co(CO)4] and [(.mu.-H)(.mu.3-S)(CO)9Os3]2(.mu.4-Hg)

5. Mercury—ruthenium mixed-metal carbonyl clusters containing 2-amido-6-methylpyridine (ampy) as a μ3,η2-ligand. Crystal structures of [Ru6(μ4-Hg)(μ3-ampy)2(CO)18]·2C4H8O and [Ru3(μ-HgBr)(μ3-ampy)(CO)9]

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