Sequential C−H and C−Ru Bond Formation and Cleavage during the Thermally Induced Rearrangement of Aryl Ruthenium(II) Complexes with [C6H3(CH2NMe2)2-2,6]- as a Bidentate η2-C,N Coordinated Ligand. The Crystal Structures of the Isomeric Pairs [RuCl{η6-C10H14}{η2-C,N-C6H3(CH2NMe2)2-2,n}] (n = 4 or 6) and [Ru(η5-C5H5){η2-C,N-C6H3(CH2NMe2)2-2,n}(PPh3)] (n = 4 or 6)-Reference-Cited by-同舟云学术

Sequential C−H and C−Ru Bond Formation and Cleavage during the Thermally Induced Rearrangement of Aryl Ruthenium(II) Complexes with [C6H3(CH2NMe2)2-2,6]- as a Bidentate η2-C,N Coordinated Ligand. The Crystal Structures of the Isomeric Pairs [RuCl{η6-C10H14}{η2-C,N-C6H3(CH2NMe2)2-2,n}] (n = 4 or 6) and [Ru(η5-C5H5){η2-C,N-C6H3(CH2NMe2)2-2,n}(PPh3)] (n = 4 or 6)

Published:1998-09-25 Issue:21 Volume:17 Page:4680-4693
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Steenwinkel Pablo¹,James Stuart L.¹,Gossage Robert A.¹,Grove David M.¹,Kooijman Huub¹,Smeets Wilberth J. J.¹,Spek Anthony L.¹,van Koten Gerard¹

Affiliation:

1. Debye Institute, Department of Metal-Mediated Synthesis, and Bijvoet Institute for Biomolecular Research, Department of Crystal and Structural Chemistry, Utrecht University, Padualaan 8, 3584 CH, Utrecht, The Netherlands

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om980343u

Reference68 articles.

1. Tuning the reactivity of metals held in a rigid ligand environment

2. Recent Findings in Cyclometallation of meta-Substituted Aryl Ligands by Platinum Group Metal Complexes by Caryl-R Bond Activation (R=H, CR3, SiR3)

3. Double Cyclometalation via Carbon−Silicon Bond Cleavage by Palladium(II) Acetate. X-ray Structure of a Cationic 1,4-Dipalladated Benzene Ring and Selective Synthesis of Heterobimetallic 1,4-Phenylene-Bridged Platinum(II)−Palladium(II) Complexes

4. Hypercoordinate Aryltrialkylsilanes and -stannanes and Their Use in the Synthesis of Homodinuclear Organometallic Complexes with a 1,4-Phenylene Bridge

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