Ketene-Forming Eliminations from Aryl Phenylacetates Promoted by R2NH/R2NH2+ in Aqueous MeCN. Mechanistic Borderline between E2 and E1cb
Author:
Affiliation:
1. Departments of Chemistry, Korea University, 1-Anamdong, Seoul, 136-701, Korea, and Pukyong National University, Pusan 608-737, Korea
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo025555m
Reference30 articles.
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3. General base catalysis, structure-reactivity interactions, and merging of mechanisms for elimination reactions of (2-arylethyl)quinuclidinium ions
4. Borderline between E1cB and E2 mechanisms. Elimination of hydrogen chloride from fluorene derivatives
5. Borderline between E1 and E2 mechanisms. Bimolecular base-promoted elimination via ion pairs competing with concerted E2 elimination
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