Stereodivergent Syntheses of (Z)- and (E)-Alkenylsilanes via Hydrosilylation of Terminal Alkynes Catalyzed by Rhodium(I) Iodide Complexes and Application to Silicon-Containing Polymer Syntheses
Author:
Affiliation:
1. Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama 226-8503, Japan
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om049922r
Reference62 articles.
1. (b) Hiyama T.; Kusumoto T. InComprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon: Oxford, 1991; Vol. 8 pp 763−792.
2. A convenient and novel route to bis(.eta.-alkyne)platinum(0) and other platinum(0) complexes from Speier's hydrosilylation catalyst H2[PtCl6].xH2O. X-ray structure of [Pt{(.eta.-CH2=CHSiMe2)2O}(P-t-Bu3)]
3. Quaternary onium hexachloroplatinates: novel hydrosilylation catalysts
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