Phosphomethylpyrimidine Synthase (ThiC): Trapping of Five Intermediates Provides Mechanistic Insights on a Complex Radical Cascade Reaction in Thiamin Biosynthesis-Reference-Cited by-同舟云学术

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Phosphomethylpyrimidine Synthase (ThiC): Trapping of Five Intermediates Provides Mechanistic Insights on a Complex Radical Cascade Reaction in Thiamin Biosynthesis

Published:2024-05-13 Issue:5 Volume:10 Page:988-1000
ISSN:2374-7943
Container-title:ACS Central Science
language:en
Short-container-title:ACS Cent. Sci.

Author:

Sharma Vishav¹^ORCID,Fedoseyenko Dmytro¹,Joshi Sumedh¹^ORCID,Abdelwahed Sameh¹,Begley Tadhg P.¹^ORCID

Affiliation:

1. Department of Chemistry, Texas A&M University, College Station, Texas 77842, United States

Funder

Welch Foundation

National Institutes of Health

Publisher

American Chemical Society (ACS)

Link

https://pubs.acs.org/doi/pdf/10.1021/acscentsci.4c00125

Reference60 articles.

1. The Structural and Biochemical Foundations of Thiamin Biosynthesis

2. Thiamin Biosynthesis

3. Biosynthesis of the Thiamin Thiazole in Bacillus subtilis: Identification of the Product of the Thiazole Synthase-Catalyzed Reaction

4. A Missing Enzyme in Thiamin Thiazole Biosynthesis: Identification of TenI as a Thiazole Tautomerase

5. Saccharomyces cerevisiae THI4p is a suicide thiamine thiazole synthase

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