Double Geminal C−H Activation and Reversible α-Elimination in 2-Aminopyridine Iridium(III) Complexes: The Role of Hydrides and Solvent in Flattening the Free Energy Surface-Reference-Cited by-同舟云学术

Double Geminal C−H Activation and Reversible α-Elimination in 2-Aminopyridine Iridium(III) Complexes: The Role of Hydrides and Solvent in Flattening the Free Energy Surface

Published:2004-06-24 Issue:28 Volume:126 Page:8795-8804
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Clot Eric¹,Chen Junyi¹,Lee Dong-Heon¹,Sung So Young¹,Appelhans Leah N.¹,Faller Jack W.¹,Crabtree Robert H.¹,Eisenstein Odile¹

Affiliation:

1. Contribution from the Sterling Chemistry Laboratory, Yale University, New Haven, Connecticut 06520-810; LSDSMS, UMR 5636, Université Montpellier 2, 34095 Montpellier Cedex 5, France; and Department of Chemistry, Chonbuk National University, Chonju, 561-756, Korea

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja048473j

Reference32 articles.

1. Recent Developments in Tritium Incorporation for Radiotracer Studies

2. Direct tritium labeling of multifunctional compounds using organoiridium catalysis. 2.

3. Inter- vs. intramolecular carbon-hydrogen activation: a carbon-hydrogen-iridium bridge in [IrH2(mq)L2]BF4 and a CH + M .fwdarw. CMH reaction trajectory

4. Reversible α-elimination in the conversion of N–CH3 to N–CHIr by double C–H activation

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