Formal Synthesis of (+)-Lasubine II and (−)-Subcosine II via Organocatalytic Michael Addition of a Ketone to an α-Nitrostyrene
Author:
Affiliation:
1. Department of Chemistry, Memorial University, St. John’s, Newfoundland, Canada A1B 3X7
Funder
Natural Sciences and Engineering Research Council of Canada
Canada Foundation for Innovation
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.5b02677
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1. Lythraceous alkaloids. X. Alkaloids of Lagerstroemia subcostata and L. favriei: A contribution to the chemotaxonomy.
2. Alkaloids from Heimia salicifolia
3. Lythraceae alkaloids. VII. Structure and stereochemistry of the biphenyl alkaloids of Decodon and Hemia
4. Enantiodivergent Synthetic Entry to the Quinolizidine Alkaloid Lasubine II
5. Enantioselective Rhodium-Catalyzed [2+2+2] Cycloaddition of Alkenyl Isocyanates and Terminal Alkynes: Application to the Total Synthesis of (+)-Lasubine II
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