Catalytic, Transition-Metal-Free Semireduction of Propiolamide Derivatives: Scope and Mechanistic Investigation
Author:
Affiliation:
1. Department of Chemistry, Virginia Tech, Blacksburg, Virginia 24061, United States
Funder
Division of Chemistry
Chemistry Department, Virginia Polytechnic Institute and State University
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.0c02567
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1. Highly Chemo- and Stereoselective Palladium-Catalyzed Transfer Semihydrogenation of Internal Alkynes Affording cis-Alkenes
2. Convenient Transfer Semihydrogenation Methodology for Alkynes Using a PdII-NHC Precatalyst
3. Selective Homogeneous Palladium(0)-Catalyzed Hydrogenation of Alkynes to (Z)-Alkenes
4. Transfer Semihydrogenation of Alkynes Catalyzed by a Zero-Valent Palladium N-Heterocyclic Carbene Complex
5. Metal-Ligand Core-Shell Nanocomposite Catalysts for the Selective Semihydrogenation of Alkynes
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