From Acyclic Intramolecular-[4 + 2]- to Transannular Bis-[4 + 2]-Cycloaddition of the Macrodiolide for the Stereoselective Synthesis of the Octahydronaphthalene Core of Polyenic Macrolactam Sagamilactam
Author:
Affiliation:
1. CINBIO, Departamento de Química Orgánica, Universidade de Vigo, 36310 Vigo, Spain
Funder
Ministerio de Ciencia e Innovaci?n
European Regional Development Fund
Xunta de Galicia
Publisher
American Chemical Society (ACS)
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.4c02239
Reference27 articles.
1. Anti-trypanosomal compound, sagamilactam, a new polyene macrocyclic lactam from Actinomadura sp. K13-0306
2. Natural products containing ‘decalin’ motif in microorganisms
3. Biocatalytic Strategies towards [4+2] Cycloadditions
4. Natural polyenic macrolactams and polycyclic derivatives generated by transannular pericyclic reactions: optimized biogenesis challenging chemical synthesis
5. The Diels-Alder Reaction in Total Synthesis
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