Difluorocarbene-Triggered Acyl Rearrangement Reaction: A Strategy for the Direct Introduction of the <i>gem</i>-Difluoromethylene Group-Reference-Cited by-同舟云学术

Difluorocarbene-Triggered Acyl Rearrangement Reaction: A Strategy for the Direct Introduction of the gem-Difluoromethylene Group

Published:2022-12-22 Issue:1 Volume:25 Page:99-103
ISSN:1523-7060
Container-title:Organic Letters
language:en
Short-container-title:Org. Lett.

Author:

Cui Haitao¹,Ban Caijin¹,Zhu Fengting¹,Yuan Jingmei¹,Du Juan¹,Huang Yanmin¹,Xiao Qi¹,Huang Chusheng¹,Huang Jun¹^ORCID,Zhu Qiang¹²^ORCID

Affiliation:

1. Guangxi Key Laboratory of Natural Polymer Chemistry and Physics, Nanning Normal University, Nanning, Guangxi 530100, People’s Republic of China

2. State Key Laboratory of Respiratory Disease, Guangzhou Institutes of Biomedicine and Health, Chinese Academy of Sciences, Guangzhou, Guangdong 510530, People’s Republic of China

Funder

Guangdong Science and Technology Department

Bagui Scholars Program of Guangxi Zhuang Autonomous Region

Natural Science Foundation of Guangxi Province

Guangxi Province

Guangxi Zhuang Autonomous Region

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.2c03907

Reference47 articles.

1. Effect of gem ‐Difluorination on the Key Physicochemical Properties Relevant to Medicinal Chemistry: The Case of Functionalized Cycloalkanes

2. Transition-Metal (Cu, Pd, Ni)-Catalyzed Difluoroalkylation via Cross-Coupling with Difluoroalkyl Halides

3. Recent progress on selective deconstructive modes of halodifluoromethyl and trifluoromethyl-containing reagents

4. Multiple-fold C–F bond functionalization for the synthesis of (hetero)cyclic compounds: fluorine as a detachable chemical handle

5. Recent Advances in the Synthetic Application of Difluorocarbene

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