Atropisomeric Chiral Diiododienes (Z,Z)-2,3-Di(1-iodoalkylidene)tetralins: Synthesis, Enantiomeric Resolution, and Application in Asymmetric Catalysis

Author:

Ogasawara Masamichi12ORCID,Sasa Hirotaka3,Hu Hao12,Amano Yuta3,Nakajima Hikaru2,Takenaga Naoko4,Nakajima Kiyohiko5,Kita Yasuyuki6,Takahashi Tamotsu2ORCID,Dohi Toshifumi3

Affiliation:

1. Department of Natural Science, Graduate School of Science and Technology, Tokushima University, Tokushima 770-8506, Japan

2. Institute for Catalysis and Graduate School of Life Science, Hokkaido University, Kita-ku, Sapporo 001-0021, Japan

3. College of Pharmaceutical Sciences, Ritsumeikan University, 1-1-1 Nojihigashi, Kusatsu, Shiga 525-8577, Japan

4. Faculty of Pharmacy, Meijo University, 150 Yagotoyama, Tempaku-ku, Nagoya, 468-8503, Japan

5. Department of Chemistry, Aichi University of Education, Igaya, Kariya, Aichi 448-8542, Japan

6. Research Organization of Science and Technology, Ritsumeikan University, 1-1-1 Nojihigashi, Kusatsu, Shiga 525-8577, Japan

Funder

Ministry of Education, Culture, Sports, Science and Technology

Asahi Glass Foundation

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference64 articles.

1. aKuhn, R.InStereochemie;Freudenberg, K., Ed.Franz Deuticke:Leipzig, 1933; pp803–824.

2. bEliel, E. L.; Wilen, S. H.; Doyle, M. P.Basic Organic Stereochemistry;Wiley Interscience:New York, 2001; pp622–632.

3. cWolf, C.Dynamic Stereochemistry of Chiral Compounds - Principles and Applications;RSC Publishing:Cambridge, 2008; pp84–109.

4. LXXI.—The molecular configurations of polynuclear aromatic compounds. Part I. The resolution of γ-6 : 6′-dinitro- and 4 : 6 : 4′ : 6′-tetranitro-diphenic acids into optically active components

5. Atropisomerism, biphenyls and the Suzuki coupling: peptide antibiotics

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