Asymmetric CuI-Catalyzed Insertion Reaction of 1-Aryl-2,2,2-trifluoro-1-diazoethanes into Si

Asymmetric CuI-Catalyzed Insertion Reaction of 1-Aryl-2,2,2-trifluoro-1-diazoethanes into Si–H Bonds

Published:2019-10-28 Issue:22 Volume:21 Page:9094-9098
ISSN:1523-7060
Container-title:Organic Letters
language:en
Short-container-title:Org. Lett.

Author:

Carreras Virginie¹^ORCID,Besnard Claire¹^ORCID,Gandon Vincent²³^ORCID,Ollevier Thierry¹^ORCID

Affiliation:

1. Département de Chimie, Pavillon Alexandre-Vachon, Université Laval, 1045 avenue de la Médecine, Québec, QC, G1V 0A6, Canada

2. ICMMO, CNRS UMR 8182, and Laboratoire de Chimie Moléculaire (LCM), CNRS UMR 9168, Univ. Paris-Sud, Université Paris-Saclay, bâtiment 420, 91405 Orsay Cedex, France

3. Institut Polytechnique de Paris, École Polytechnique, route de Saclay, 91128 Palaiseau Cedex, France

Funder

Universit? Laval

Natural Sciences and Engineering Research Council of Canada

Centre in Green Chemistry and Catalysis

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.9b03480

Reference54 articles.

1. Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

2. Application of donor/acceptor-carbenoids to the synthesis of natural products

3. Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

4. Vinylogous Aldol Products from Chiral Crotylsilanes Obtained by Enantioselective Rh(II) and Cu(I) Carbenoid Si−H Insertion

5. Quest for Novel Chemical Entities through Incorporation of Silicon in Drug Scaffolds

Cited by 24 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Transition‐Metal‐Catalyzed Reactions Involving Trifluoro Diazo Compounds and Their Surrogates;European Journal of Organic Chemistry;2024-06-28

2. Enantioselective Si−H Insertion of Arylvinyldiazoesters Promoted by Rhodium(I)/Diene Complexes;Advanced Synthesis & Catalysis;2024-05-15

3. The Use of DMC as Green Solvent in Organic Synthesis;Green Solvents in Organic Synthesis;2024-03-08

4. The role of silicon in drug discovery: a review;RSC Medicinal Chemistry;2024

5. Recent Progress on Copper-Catalyzed C–C Bond Formation via C(sp2)–H Insertions Using Diazo and Related Compounds;Synthesis;2023-07-20