Catalytic Amide–Base System of TMAF and N(TMS)3 for Deprotonative Coupling of Benzylic C(sp3)–H Bonds with Carbonyls
Author:
Affiliation:
1. Department of Biophysical Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, Aoba, Sendai, 980-8578, Japan
Funder
Japan Agency for Medical Research and Development
Sumitomo Foundation
Japan Society for the Promotion of Science
Yamaguchi Educational and Scholarship Foundation
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.9b00550
Reference80 articles.
1. The 2×3 Toolbox of Organometallic Methods for Regiochemically Exhaustive Functionalization
2. Deprotonative Metalation Using Ate Compounds: Synergy, Synthesis, and Structure Building
3. Regio- and Chemoselective Metalation of Arenes and Heteroarenes Using Hindered Metal Amide Bases
4. C–H Functionalization of Azines
5. Heterocycle-Mediated ortho-Functionalization of Aromatic Compounds: The DoM Methodology and Synthetic Utility
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