Syntheses of Unsymmetrical 1,4-Bifunctional Allylboron Reagents via Cu-catalyzed Highly Regio- and Stereoselective 1,4-Protoboration of Dienylboronates and Analysis of the Origin of Chemoselective Aldehyde syn-(Hydroxymethyl)allylation
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, Auburn University, Auburn, Alabama 36849, United States
Funder
Auburn University
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.8b03483
Reference64 articles.
1. Selective reactions using allylic metals
2. bDenmark, S. E.; Almstead, N. G. In Modern Carbonyl Chemistry; Otera, J., Ed. Wiley-VCH: Weinheim, 2000; p 299.
3. cChemler, S. R.; Roush, W. R. In Modern Carbonyl Chemistry; Otera, J., Ed. Wiley-VCH: Weinheim, 2000; p 403.
4. Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones
5. Allylboration of Carbonyl Compounds
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