Syntheses of Unsymmetrical 1,4-Bifunctional Allylboron Reagents via Cu-catalyzed Highly Regio- and Stereoselective 1,4-Protoboration of Dienylboronates and Analysis of the Origin of Chemoselective Aldehyde syn-(Hydroxymethyl)allylation

Author:

Gao Shang1,Wang Mengzhou1,Chen Ming1ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Auburn University, Auburn, Alabama 36849, United States

Funder

Auburn University

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference64 articles.

1. Selective reactions using allylic metals

2. bDenmark, S. E.; Almstead, N. G. In Modern Carbonyl Chemistry; Otera, J., Ed. Wiley-VCH: Weinheim, 2000; p 299.

3. cChemler, S. R.; Roush, W. R. In Modern Carbonyl Chemistry; Otera, J., Ed. Wiley-VCH: Weinheim, 2000; p 403.

4. Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones

5. Allylboration of Carbonyl Compounds

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