Construction of Vicinal All-Carbon Stereogenic Centers via Copper-Catalyzed Asymmetric Decarboxylative Propargylation: Enantio- and Diastereoselective Synthesis of Substituted Spirolactones
Author:
Affiliation:
1. Engineering Center of Catalysis and Synthesis for Chiral Molecules, Fudan University, 200433 Shanghai, China
2. Shanghai Engineering Center of Industrial Catalysis for Chiral Drugs, 200433 Shanghai, China
Funder
Ministry of Science and Technology of the People's Republic of China
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.2c04113
Reference34 articles.
1. Enantioselective formation of quaternary carbon stereocenters in natural product synthesis: a recent update
2. Catalytic enantioselective construction of vicinal quaternary carbon stereocenters
3. Contiguous stereogenic quaternary carbons: A daunting challenge in natural products synthesis
4. Organo-Cation Catalyzed Asymmetric Homo/Heterodialkylation of Bisoxindoles: Construction of Vicinal All-Carbon Quaternary Stereocenters and Total Synthesis of (−)-Chimonanthidine
5. Construction of Multiple, Contiguous Quaternary Stereocenters in Acyclic Molecules by Lithiation-Borylation
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