Copper-Catalyzed Umpolung of <i>N</i>-2,2,2-Trifluoroethylisatin Ketimines for the Enantioselective 1,3-Dipolar Cycloaddition with Benzo[<i>b</i>]thiophene Sulfones-Reference-Cited by-同舟云学术

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Copper-Catalyzed Umpolung of N-2,2,2-Trifluoroethylisatin Ketimines for the Enantioselective 1,3-Dipolar Cycloaddition with Benzo[b]thiophene Sulfones

Published:2022-06-15 Issue:25 Volume:24 Page:4603-4608
ISSN:1523-7060
Container-title:Organic Letters
language:en
Short-container-title:Org. Lett.

Author:

Yuan Wei-Cheng¹^ORCID,Yang Lei¹²,Zhao Jian-Qiang¹^ORCID,Du Hong-Yan³,Wang Zhen-Hua¹^ORCID,You Yong¹^ORCID,Zhang Yan-Ping¹,Liu Jiabin⁴,Zhang Wenjing⁴^ORCID,Zhou Ming-Qiang²

Affiliation:

1. Innovation Research Center of Chiral Drugs, Institute for Advanced Study, Chengdu University, Chengdu 610106, China

2. National Engineering Research Center of Chiral Drugs, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China

3. Institute of Forensic Science, Ministry of Public Security, Beijing 100038, China

4. Green Catalysis Center and College of Chemistry, Zhengzhou University, Zhengzhou, Henan 450001, China

Funder

Chengdu University

National Natural Science Foundation of China

Sichuan Science and Technology Program

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.2c01716

Reference49 articles.

1. Umpolung of the Reactivity of Carbonyl Compounds Through Sulfur-Containing Reagents

2. Methods of Reactivity Umpolung

3. α-Amino Radicals via Photocatalytic Single-Electron Reduction of Imine Derivatives

4. An Organocatalytic Biomimetic Strategy Paves the Way for the Asymmetric Umpolung of Imines

5. N-Heterocyclic carbene catalysed umpolung reactions of imines approaching enantioselective synthesis

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1. Asymmetric Cycloaddition of N-2,2,2-Trifluoroethylisatin Ketimines and Unsymmetrical Dicarbonyl-Activated Alkenes: Construction of 5′-Trifluoromethylated 3,2′-Pyrrolidinyl Spirooxindoles with Three Carbonyl Groups;The Journal of Organic Chemistry;2024-08-28

2. Design of Synthetic Strategies towards Sulfur Containing Scaffolds;Synthesis;2024-08-28

3. Copper-Catalyzed Asymmetric [3 + 2] Cycloaddition of N-2,2,2-Trifluoroethylisatin Ketimines to Access Three Classes of Polyfunctionalized Spiro-Pyrrolidine–Oxindole Motifs;Organic Letters;2024-08-22

4. Chiral-Boron Complex-Catalyzed Asymmetric [3 + 2] Cycloaddition of 2′-Hydroxychalcones with N-2,2,2-Trifluoroethylisatin Ketimines;The Journal of Organic Chemistry;2024-08-01

5. Chiral Brønsted Base Activation of Donor–Acceptor Cyclopropanes toward Diastereo- and Enantioselective [3 + 2] Cycloaddition with Isatin-Derived Ketimines;The Journal of Organic Chemistry;2024-06-10

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