Enantioselective Mukaiyama–Michael Reaction of Cyclic α-Alkylidene β-Keto Phosphine Oxide and Phosphonate and Asymmetric Synthesis of (R)-Homosarkomycin
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, 3-4-1 Ohkubo, Shinjuku-ku, Tokyo 169-8555, Japan
Funder
Ministry of Education, Culture, Sports, Science and Technology
Waseda University
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.6b03798
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1. Enantioselective catalytic Diels–Alder reaction of ethyl 2-benzoylacrylate with chiral bis(oxazoline)– or mono(oxazoline)–magnesium complex
2. Asymmetric Diels−Alder Reactions of Unsaturated β-Ketoesters Catalyzed by Chiral Ruthenium PNNP Complexes
3. Catalytic Asymmetric [4 + 2] Cycloadditions and Hosomi–Sakurai Reactions of α-Alkylidene β-Keto Imides
4. Highly Enantioselective Catalytic Asymmetric [2+2] Cycloadditions of Cyclic α-Alkylidene β-Oxo Imides with Ynamides
5. Silver(I)-Catalyzed Enantioselective [3+2]-Cycloaddition Reaction of α-Silylimines: A Facile Route to Quaternary-Carbon-Rich Scaffolds
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