Diastereoselective Intramolecular Carbolithiations of Stereodefined Secondary Alkyllithiums Bearing a Remote Alkynylsilane
Author:
Affiliation:
1. Department of Chemistry, Ludwig-Maximilians-Universität, Butenandtstrasse 5-13, 81377 Munich, Germany
Funder
Deutsche Forschungsgemeinschaft
Verband der Chemischen Industrie
Albemarle Corporation
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.8b01290
Reference51 articles.
1. Butyllithium-induced cyclotrimerisation reactions of organic nitriles: solvent dependency, crystal and solution structures of lithio triazine intermediates and an unexpected rearrangement of dihydrotriazino anions
2. Synthesis and Reactivity of sp2 Geminated Organobismetallic Derivatives
3. Tandem Intermolecular - Intramolecular Carbolithiation: A Versatile Method for Synthesis of Cyclopentanes
4. Intramolecular Carbolithiation Reactions for the Preparation of Azabicyclo[2.2.1]heptanes
5. Cyclization by Intramolecular Carbolithiation of Alkyl- and Vinyllithiums Prepared by Reductive Lithiation: Surprising Stereochemistry in the Lithium Oxyanion Accelerated Cyclization
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