Copper-Catalyzed Double C(sp3)–Si Coupling of Geminal Dibromides: Ionic-to-Radical Switch in the Reaction Mechanism
Author:
Affiliation:
1. Institut für Chemie, Technische Universität Berlin, Strasse des 17. Juni 115, 10623 Berlin, Germany
Funder
Deutsche Forschungsgemeinschaft
Einstein Stiftung Berlin
Alexander von Humboldt-Stiftung
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.8b02281
Reference29 articles.
1. Geminal bis(boron) compounds: Their preparation and synthetic applications
2. gem-Diborylalkanes: recent advances in their preparation, transformation and application
3. Copper(I)-Catalyzed Boryl Substitution of Unactivated Alkyl Halides
4. A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates
5. Synthesis of 1,1-Organodiboronates via Rh(I)Cl-Catalyzed Sequential Regioselective Hydroboration of 1-Alkynes
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