Tuning of α-Silyl Carbocation Reactivity into Enone Transposition: Application to the Synthesis of Peribysin D, E-Volkendousin, and E-Guggulsterone-Reference-Cited by-同舟云学术

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Tuning of α-Silyl Carbocation Reactivity into Enone Transposition: Application to the Synthesis of Peribysin D, E-Volkendousin, and E-Guggulsterone

Published:2021-08-13 Issue:17 Volume:23 Page:6642-6647
ISSN:1523-7060
Container-title:Organic Letters
language:en
Short-container-title:Org. Lett.

Author:

Athawale Paresh R.¹²,Zade Vishal M.¹²,Rama Krishna Gamidi¹^ORCID,Reddy D. Srinivasa¹²³^ORCID

Affiliation:

1. Organic Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

3. CSIR-Indian Institute of Integrative Medicine, Canal Road, Jammu 180001, India

Funder

Council of Scientific and Industrial Research

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.1c02173

Reference44 articles.

1. The functional group selectivity of complex hydride reducing agents

2. Organic synthesis using bridgehead carbocations and bridgehead enones

3. The oxa-Michael reaction: from recent developments to applications in natural product synthesis

4. Construction of all-carbon quaternary stereocenters by catalytic asymmetric conjugate addition to cyclic enones in natural product synthesis

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1. Guggulsterone – a potent bioactive phytosteroid: synthesis, structural modification, and its improved bioactivities;RSC Medicinal Chemistry;2024

2. Amidative Cyclization of Alkynyl Esters to Access Pyrazin-1(2H)-ones: Application to the Synthesis of Peramine and Dibromophakellin;The Journal of Organic Chemistry;2023-12-05

3. Direct Deoxygenation of α-Hydroxy and α,β-Dihydroxy Ketones Using a Silyl Lithium Reagent;The Journal of Organic Chemistry;2023-09-20

4. Scalable Synthesis of Silacyclohexanones and Ready Access to Silicon Building Blocks;Organic Letters;2023-09-08

5. Design, synthesis, and biological evaluation of new heterocycles bearing both silicon and phosphorus as potent MMP ‐2 inhibitors;Journal of the Chinese Chemical Society;2022-11

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