Photodissociation of the Product from a Transition-Metal Center Allows the Catalytic Cycle to Proceed: The Rhodium(I)-Catalyzed [2+2+1] Carbonylative Cycloaddition of Diynes
Author:
Affiliation:
1. Division of Materials Science, Nara Institute of Science and Technology (NAIST), Ikoma, Nara 630-0192, Japan
2. Academic Assembly, Faculty of Pharmaceutical Sciences, University of Toyama, 2630 Sugitani, Toyama 930-0194, Japan
Funder
Nara Institute of Science and Technology
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.1c01631
Reference38 articles.
1. Carbon-hydrogen activation in completely saturated hydrocarbons: direct observation of M + R-H .fwdarw. M(R)(H)
2. Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups
3. A flash photolysis investigation of dihydrogen elimination from phosphine complexes of iridium(III) and rhodium(III): H2IrCl(CO)(PPh3)2, H2IrCl(PPh3)3, and H2RhCl(PPh3)3
4. Reaction of carbon-hydrogen bonds in alkanes with bis(diphosphine) complexes of iron
Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Rhodium(I)-Catalyzed [2+2+1]-Carbonylative Cycloaddition of Diynes with Anthracene α-Diketone as the Source of CO;Synlett;2022-09-07
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