Spectroscopic Identification of an FeIII Center, not FeIV, in the Crystalline Sc–O–Fe Adduct Derived from [FeIV(O)(TMC)]2+
Author:
Affiliation:
1. Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, Minnesota 55455, United States
2. Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, United States
Funder
Division of Chemistry
University of Minnesota
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.5b00535
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1. Mn4Ca Cluster in Photosynthesis: Where and How Water is Oxidized to Dioxygen
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5. Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters
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