Phosphinoalkylidene and -alkylidyne Complexes of Titanium: Intermolecular C–H Bond Activation and Dehydrogenation Reactions
Author:
Affiliation:
1. Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, United States
2. Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington, Indiana 47405, United States
Funder
University of Pennsylvania
Japan Society for the Promotion of Science
Division of Chemistry
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.5b06973
Reference49 articles.
1. Novel Metal−Carbon Multiply Bonded Twelve-Electron Complexes of Ti and Zr Supported by a Bis(Phosphoranimine) Chelate
2. The first hafnium methandiide complexes: the assembly of an entire triad of group 4 metal ‘pincer’ bis(phosphinimine) complexes possessing the MC carbene–ylide structure
3. The First Biscarbene Complex of a Group 4 Metal: [Zr{C(Me2P=NSiMe3)2}2] We thank the Natural Sciences and Engineering Research Council of Canada, NOVA Chemicals Corp., and the University of Alberta for financial support.
4. Nucleophilic Reactivity of the Multiply Bonded Carbon Center in Group 4−Pincer Bis(iminophosphorano)methanediide Complexes
5. New Zirconium Hydrocarbyl Bis(phosphoranimino) “Pincer” Carbene Complexes
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