Mechanistic Details of Pd(II)-Catalyzed C–H Iodination with Molecular I2: Oxidative Addition vs Electrophilic Cleavage-Reference-Cited by-同舟云学术

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Mechanistic Details of Pd(II)-Catalyzed C–H Iodination with Molecular I2: Oxidative Addition vs Electrophilic Cleavage

Published:2015-07-14 Issue:28 Volume:137 Page:9022-9031
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Haines Brandon E.¹,Xu Huiying¹,Verma Pritha²,Wang Xiao-Chen²,Yu Jin-Quan²,Musaev Djamaladdin G.¹

Affiliation:

1. Cherry L. Emerson Center for Scientific Computation, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States

2. Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, United States

Funder

Center for Selective C-H Functionalization, National Science Foundation

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.5b03410

Reference128 articles.

1. Co(III)-Catalyzed C–H Activation/Formal SN-Type Reactions: Selective and Efficient Cyanation, Halogenation, and Allylation

2. Regio- and Chemoselective CH Chlorination/Bromination of Electron-Deficient Arenes by Weak Coordination and Study of Relative Directing-Group Abilities

3. High-Yielding, Versatile, and Practical [Rh(III)Cp*]-CatalyzedOrthoBromination and Iodination of Arenes

4. Mild CH Halogenation of Anilides and the Isolation of an Unusual Palladium(I)-Palladium(II) Species

5. Bystanding F+ Oxidants Enable Selective Reductive Elimination from High-Valent Metal Centers in Catalysis

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