Phosphine-Catalyzed Doubly Stereoconvergent γ-Additions of Racemic Heterocycles to Racemic Allenoates: The Catalytic Enantioselective Synthesis of Protected α,α-Disubstituted α-Amino Acid Derivatives
Author:
Affiliation:
1. Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States
Funder
National Institute of General Medical Sciences
Vetenskapsrådet
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.5b05528
Reference28 articles.
1. Chiral phosphines in nucleophilic organocatalysis
2. bFan, Y. C.; Kwon, O.InScience of Synthesis: Asymmetric Organocatalysis;List, B.; Maruoka, K., Eds.Georg Thieme Verlag:Stuttgart, 2012; Vol.1, pp723–782.
3. Novel "Umpolung" in C-C Bond Formation Catalyzed by Triphenylphosphine
4. Phosphine-Catalyzed Isomerization-Addition of Oxygen Nucleophiles to 2-Alkynoates
5. Phosphine-Catalyzed Enantioselective Synthesis of Oxygen Heterocycles
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