Synthesis and Reactivity of Novel Niobocene Complexes Containing Allyl or 1-Azaallyl Ligands. X-ray Crystal Structure of [Li{η3-N(SiMe3)C(tBu)CH2}]3-Reference-Cited by-同舟云学术

Synthesis and Reactivity of Novel Niobocene Complexes Containing Allyl or 1-Azaallyl Ligands. X-ray Crystal Structure of [Li{η3-N(SiMe3)C(tBu)CH2}]3

Published:1998-12-01 Issue:26 Volume:17 Page:5874-5879
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Antiñolo Antonio¹,Huertas Carmen¹,del Hierro Isabel¹,Lappert Michael F.¹,Otero Antonio¹,Prashar Sanjiv¹,Rodriguez Ana M.¹,Villaseñor Elena¹

Affiliation:

1. Departamento de Química Inorgánica, Orgánica y Bioquímica, Facultad de Químicas, Campus Universitario, Universidad de CastillaLa Mancha, 13071-Ciudad Real, Spain, and The Chemistry Laboratory, University of Sussex, Brighton BN1 9QJ, U.K.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om980716r

Reference31 articles.

1. Recent studies on metal and metalloid bis(trimethylsilyl)methyls and the transformation of the bis(trimethylsilyl)methyl into the azaallyl and β-diketinimato ligands

2. Transformation of the bis(trimethylsilyl)methyl into aza-allyl and β-diketinimato ligands; the X-ray structures of [Li{N(R)C(But)CH(R)}]2and [Zr{N(R)C(But)CHC(Ph)N(R)}Cl3](R = SiMe3)

3. Unusual [2 + 2] cycloaddition adducts of an imidovanadium complex with alkynes and ethene: conversion to .eta.3-1-azaallyl and ethenyl complexes

4. Ligand redistribution reactions as a route to cyclopentadienyl- or 1-aza-allylzirconium(IV) trichlorides and the x-ray structures of [{Cl2(μ-Cl)}2 and [2Cl2] LL′ = N(R)C(But)CHR, R=SiMe3]

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