In Situ Formed “Weakly Ligated/Labile Ligand” Iridium(0) Nanoparticles and Aggregates as Catalysts for the Complete Hydrogenation of Neat Benzene at Room Temperature and Mild Pressures

Author:

Bayram Ercan1,Zahmakıran Mehmet2,Özkar Saim2,Finke Richard G.1

Affiliation:

1. Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523

2. Department of Chemistry, Middle East Technical University, 06531 Ankara, Turkey

Publisher

American Chemical Society (ACS)

Subject

Electrochemistry,Spectroscopy,Surfaces and Interfaces,Condensed Matter Physics,General Materials Science

Reference70 articles.

1. aThe nomenclature “nanoparticle” is used herein rather than “nanocluster”. Although as Schmid and Fenske have noted there is at present no “sharp discrimination”(1b)between these two terms, there is an evolving nomenclature where nanocluster is preferred when the composition and the structure of the species are precisely defined whereas nanoparticle is more appropriate when a size distribution is present.(1b)However, reports exist where “nanoparticle” has been used to designate very precisely defined species.(1c, 1d)

2. Metal clusters and nanoparticles

3. Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 Å Resolution

4. Crystal Structure of the Gold Nanoparticle [N(C8H17)4][Au25(SCH2CH2Ph)18]

5. Transition-metal nanocluster stabilization for catalysis: A critical review of ranking methods and putative stabilizers

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