Gas-Phase Bond Strength and Atomic Connectivity Studies of the Unsymmetrical Two-Center Three-Electron Ion, [Et2S∴SMe2]+

Author:

James Mary A.1,McKee Michael L.1,Illies Andreas J.1

Affiliation:

1. Contribution from the Department of Chemistry, Auburn University, Auburn University, Alabama 36849-5312

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference37 articles.

1. THE NATURE OF THE CHEMICAL BOND. II. THE ONE-ELECTRON BOND AND THE THREE-ELECTRON BOND

2. A Definitive Investigation of the Gas-Phase Two-Center Three-Electron Bond in [H2S-SH2]+, [Me2S-SMe2]+, and [Et2S-SEt2]+: Theory and Experiment

3. For leading references also see:  (a) Asmus, K.D. InSulfur-Centered Reaction Intermediates in Chemistry and Biology; Chatgilialoglu, C., Asmus, K.D., Eds.; Plenum Press:  New York, 1990; p 155. (b) Hungerbuhler, H.; Guha, S. N.; Asmus, K.D.J.Chem.Soc., Chem.Commun.1991, 999. (c) Bobrowski, K.; Schoneich, C.; Holcman, J.; Asmus, K.D.J.Chem.Soc., Perkin Trans.21991, 353. (d) Mohan, H.; Asmus, K.D.J.Phys.Chem.1988,92, 118.

4. A novel mechanism for reactions of thiirane with the thiirane radical cation. An experimental and ab initio study

5. Sulfur-sulfur bond lengths, or can a bond length be estimated from a single parameter?

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