Platinum-Catalyzed Addition of Dimethylsilylene to β-Methyl α,β-Unsaturated Ketones: γ-Silylation Forming 1-Oxa-2-silacyclohex-5-enes
Author:
Affiliation:
1. Department of Chemistry, Graduate School of Science, Sakyo, Kyoto 606-8502, Japan
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol702357n
Reference23 articles.
1. Silylenes, Silenes, and Disilenes: Novel Silicon-Based Reagents for Organic Synthesis?
2. Metal-Catalyzed Silacyclopropanation of Mono- and Disubstituted Alkenes
3. Silylene Transfer to Carbonyl Compounds and Subsequent Ireland−Claisen Rearrangements to Control Formation of Quaternary Carbon Stereocenters
4. Disproportionation of pentamethyldisilane and sym-tetramethyldisilane catalysed by platinum complexes
5. Evidence for “silylenoid” species in disproportionation of pentamethyldisilane catalyzed by trans-[PtCl2 (Et3P)2]
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2. Transition Metal-Catalyzed Selective Functionalization of Oligosilanes without Si-Si Bond Cleavage;Journal of Synthetic Organic Chemistry, Japan;2022-06-01
3. Synthesis of Disilanes, Dihydrosiloles, and 1,4‐Disilacyclohexa‐2,5‐dienes by Transition‐Metal‐Free Transfer of Diphenylsilylene and Dimethylsilylene from Silylboronic Esters;European Journal of Organic Chemistry;2022-03-23
4. Stereocontrolled Synthesis of Triols Containing Four Asymmetric Centers: Application of C,O-Chelated Germyl Enolates to a Diastereoselective Aldol Reaction;Organic Letters;2018-06-25
5. Highly regio- and stereoselective hydrosilylation of β-fluoroalkylated α,β-unsaturated ketones;Journal of Fluorine Chemistry;2015-05
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