Matrix Isolation Study into the Mechanism of Photoinduced Cyclization Reactions of Chromium Carbenes
Author:
Affiliation:
1. Department of Chemistry, National University of Ireland, Maynooth, County Kildare, Ireland
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om970495%2B
Reference32 articles.
1. Carbene Complexes in Organic Synthesis [New Synthetic Methods (47)]
2. Reaction of chromium carbene complexes with imines. Synthesis of .beta.-lactams
3. Formation of cyclobutanones by the photolytic reaction of chromium carbene complex (CO)5Cr:C(OMe)Me with electron-rich olefins
4. Synthesis, structure, and reactivity of cyclic (arene)chromium carbene complexes
5. Evidence for the intermediacy of chromium-ketene complexes in the synthesis of .beta.-lactams by the photolytic reaction of chromium-carbene complexes with imines. Use in amino acid synthesis
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1. Photo-activated CO-release in the amino tungsten Fischer carbene complex, [(CO)5WC(NC4H8)Me], picosecond time resolved infrared spectroscopy, time-dependent density functional theory, and an antimicrobial study;Journal of Inorganic Biochemistry;2020-07
2. Mechanistic Investigations of the Photochemical Isomerizations of [(CO)5MC(Me)(OMe)] (M = Cr, Mo, and W) Complexes;ACS Omega;2017-09-05
3. An investigation into the photochemistry of, and the electrochemically induced CO-loss from, [(CO)5MC(OMe)Me](M = Cr or W) using low-temperature matrix isolation, picosecond infrared spectroscopy, cyclic voltammetry, and time-dependent density functional theory;Dalton Transactions;2015
4. Direct Observation of Metal Ketenes Formed by Photoexcitation of a Fischer Carbene using Ultrafast Infrared Spectroscopy;Organometallics;2014-10-02
5. Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3];Phys. Chem. Chem. Phys.;2014-08-29
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