Kinetics of the BpCu-Catalyzed Carbene Transfer Reaction (Bp = Dihydridobis(1-pyrazolyl)borate). Is a 14-Electron Species the Real Catalyst for the General Copper-Mediated Olefin Cyclopropanation?
Author:
Affiliation:
1. Departamento de Química y Ciencia de los Materiales and Departamento de Ingeniería Química, Química Física y Química Orgánica, Universidad de Huelva, Carretera de Palos de la Frontera, s/n, 21819-Huelva, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om990270u
Reference27 articles.
1. Transition Metal Carbene Complexes: Cyclopropanation
2. Asymmetric induction in carbenoid reaction by means of a dissymmetric copper chelate
3. Catalytic asymmetric synthesis of cyclopropanecarboxylic acids: an application of chiral copper carbenoid reaction
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