Biosynthesis of Spinosyn in Saccharopolyspora spinosa: Synthesis of Permethylated Rhamnose and Characterization of the Functions of SpnH, SpnI, and SpnK-Reference-Cited by-同舟云学术

Biosynthesis of Spinosyn in Saccharopolyspora spinosa: Synthesis of Permethylated Rhamnose and Characterization of the Functions of SpnH, SpnI, and SpnK

Published:2010-02-16 Issue:9 Volume:132 Page:2901-2903
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Kim Hak Joong¹,White-Phillip Jess A.¹,Ogasawara Yasushi¹,Shin Nara¹,Isiorho Eta A.¹,Liu Hung-wen¹

Affiliation:

1. Division of Medicinal Chemistry, College of Pharmacy, Department of Chemistry and Biochemistry, and Institute of Cellular & Molecular Biology, University of Texas at Austin, Austin, Texas 78712

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja910223x

Reference20 articles.

1. A83543A-D, unique fermentation-derived tetracyclic macrolides

2. Natural products as insecticides: the biology, biochemistry and quantitative structure-activity relationships of spinosyns and spinosoids

3. bSalgado, V. L. and Sparks, T. C.InComprehensive Molecular Insect Science;Iatrou, K., Gill, S. S., and Gilbert, L. I., Eds.Pergamon:Oxford, 2005; Vol. 6, pp137−173.

4. Monomethylated: spinosyn P, W (R1= Me, R2= R3= H), spinosyn U, V (R2= Me, R1= R3= H), spinosyn T (R3= Me, R1= R2= H); dimethylated: spinosyn K, O, Y (R1= R2= Me, R3= H), J, L, M, N (R1= R3= Me, R2= H), spinosyn H, Q, R, S (R1= H, R2= R3= Me).

5. Cloning and analysis of the spinosad biosynthetic gene cluster of Saccharopolyspora spinosa11The DNA sequence reported here was deposited in GenBank under the accession number AY007564.

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