Theoretical Studies of Inorganic and Organometallic Reaction Mechanisms. 9. Intermolecular versus Intramolecular Carbon−Hydrogen Bond Activation in Zirconium, Rhodium, and Iridium Complexes
Author:
Affiliation:
1. Department of Chemistry, Texas A&M University, College Station, Texas 77843
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om950416z
Reference52 articles.
1. Carbon-hydrogen activation in completely saturated hydrocarbons: direct observation of M + R-H .fwdarw. M(R)(H)
2. Alkane dehydrogenation by iridium complexes
3. Oxidative addition of the carbon-hydrogen bonds of neopentane and cyclohexane to a photochemically generated iridium(I) complex
4. Mechanism of arene carbon-hydrogen bond activation by (C5Me5)Rh(PMe3)(H)Ph. Evidence for arene precoordination
5. Control of .eta.2-coordination vs. carbon-hydrogen bond activation by rhodium: the role of aromatic resonance energies
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