Long-Range Through-Bond Photoactivated σ Bond Cleavage in Steroids. Intramolecular Sensitized Debromination1
Author:
Affiliation:
1. Department of Chemistry, Purdue University, West Lafayette, Indiana 47907
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol990319s
Reference28 articles.
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3. Organic photochemistry. 95. Antenna-initiated photochemistry of distal groups in polyfunctional steroids. Intramolecular singlet and triplet energy transfer in 3.alpha.-(dimethylphenylsiloxy)-5.alpha.-androstan-17-one and 3.alpha.-(dimethylphenylsiloxy)-5.alpha.-androstane-11,17-dione
4. Organic photochemistry. 97. Antenna-initiated photochemistry in polyfunctional steroids. Photoepimerization of 3.alpha.-(dimethylphenylsiloxy)-5.alpha.-androstane-6,17-dione and its 3.beta. isomer by through-bond exchange energy transfer
5. Antenna-Initiated Photochemistry of Distal Groups in Trifunctional Steroids. Z.fwdarw.E Olefin Photoisomerization Involving Ketone Singlet .fwdarw. Triplet Switches by Through-Bond Energy Transfer
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