Straightforward Access to High-Performance Organometallic Catalysts by Fluoride Activation: Proof of Principle on Asymmetric Cyanation, Asymmetric Michael Addition, CO2 Addition to Epoxide, and Reductive Alkylation of Amines by Tetrahydrofuran-Reference-Cited by-同舟云学术

Straightforward Access to High-Performance Organometallic Catalysts by Fluoride Activation: Proof of Principle on Asymmetric Cyanation, Asymmetric Michael Addition, CO2 Addition to Epoxide, and Reductive Alkylation of Amines by Tetrahydrofuran

Published:2021-10-13 Issue:21 Volume:11 Page:13077-13084
ISSN:2155-5435
Container-title:ACS Catalysis
language:en
Short-container-title:ACS Catal.

Author:

Tsygankov Alexey A.¹,Chusov Denis¹^ORCID

Affiliation:

1. A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Vavilova Street 28, Moscow 119991, Russian Federation

Funder

Russian Science Foundation

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acscatal.1c03785

Reference62 articles.

1. Transition Metal Fluoride Complexes in Asymmetric Catalysis

2. Catalytic, Enantioselective Addition of Allylsilanes to Aldehydes: Generation of a Novel, Reactive TiIV Complex from TiF4

3. Apparent Catalytic Generation of Chiral Metal Enolates: Enantioselective Dienolate Additions to Aldehydes Mediated by Tol-BINAP·Cu(II) Fluoride Complexes

4. Mechanistic Insights into Cu-Catalyzed Asymmetric Aldol Reactions: Chemical and Spectroscopic Evidence for a Metalloenolate Intermediate

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