Computational Support for Phillips Catalyst Initiation via Cr–C Bond Homolysis in a Chromacyclopentane Site
Author:
Affiliation:
1. Department of Chemical Engineering, University of California, Santa Barbara, California 93106-5080, United States
2. Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106-9510, United States
Funder
Basic Energy Sciences
Division of Chemical, Bioengineering, Environmental, and Transport Systems
Publisher
American Chemical Society (ACS)
Subject
Catalysis,General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acscatal.7b03724
Reference52 articles.
1. Hogan, J. P.; Banks, R. L.Polymers and Production Thereof. U.S. Patent 2,825,721, March 4, 1958.
2. A Review of the Phillips Supported Chromium Catalyst and Its Commercial Use for Ethylene Polymerization
3. An XPS study of the Phillips Cr/silica polymerization catalyst
4. Oxidation of olefins by supported chromium oxide
5. Evidence for a chromasiloxane ring size effect in Phillips (Cr/SiO2) polymerization catalysts
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