Bioinspired, Multidisciplinary, Iterative Catalyst Design Creates the Highest Performance Peroxidase Mimics and the Field of Sustainable Ultradilute Oxidation Catalysis (SUDOC)

Author:

Warner Genoa R.1ORCID,Somasundar Yogesh1ORCID,Jansen Kyle C.1,Kaaret Evan Z.1,Weng Cindy1,Burton Abigail E.1,Mills Matthew R.1ORCID,Shen Longzhu Q.2ORCID,Ryabov Alexander D.1ORCID,Pros Gabrielle3,Pintauer Tomislav3,Biswas Saborni1,Hendrich Michael P.1ORCID,Taylor Julia A.4,Vom Saal Frederick S.4,Collins Terrence J.1ORCID

Affiliation:

1. Institute for Green Science, Department of Chemistry, 4400 Fifth Avenue, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, United States

2. University of Cambridge, Downing Street, Cambridge CB2 3EJ, United Kingdom

3. Department of Chemistry and Biochemistry, 600 Forbes Avenue, Duquesne University, Pittsburgh, Pennsylvania 15282, United States

4. Division of Biological Sciences, University of Missouri, Columbia, Missouri 65211, United States

Funder

Heinz Endowments

Heinz Family Foundation

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

Reference73 articles.

1. Targeting of High-Valent Iron-TAML Activators at Hydrocarbons and Beyond

2. Mechanistic considerations on the reactivity of green FeIII-TAML activators of peroxides

3. Designing Ligands for Oxidizing Complexes

4. TAML Oxidant Activators:  A New Approach to the Activation of Hydrogen Peroxide for Environmentally Significant Problems

5. Collins, T. J.; Denardo, M. A.; Warner, G. R.; Gordon-Wylie, S. W.; Ellis, W. C.; Somasundar, Y. Far Superior Oxidation Catalysts Based on Macrocyclic Compounds. PCT Int. Appl. WO 2017053564 A1 20170330, 2017.

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