Expanding Biocatalysis for Organosilane Functionalization: Enantioselective Nitrene Transfer to Benzylic Si–C–H Bonds
Author:
Affiliation:
1. Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States
2. Core R&D, Dow Inc., Midland, Michigan 48674, United States
Funder
Dow Chemical Company
Publisher
American Chemical Society (ACS)
Subject
Catalysis,General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acscatal.3c05370
Reference48 articles.
1. Organosilicon Biotechnology
2. Biocatalytic Transformations of Silicon—the Other Group 14 Element
3. Selective Enzymatic Oxidation of Silanes to Silanols
4. Origin and Control of Chemoselectivity in Cytochrome c Catalyzed Carbene Transfer into Si–H and N–H bonds
5. Directed evolution of cytochrome c for carbon–silicon bond formation: Bringing silicon to life
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