Surface Oxygen Vacancy and Hydride Species on Ceria Are Detrimental to Acetylene Semihydrogenation Reaction

Author:

Li Zhaorui1,Chen Lu2,Wu Zongfang3,Jia AiPing4ORCID,Shi Shucheng5,Zhang Hui6ORCID,Wang Jia2,Liu Zhi5ORCID,Shao Wei-Peng5,Yang Fan5ORCID,Wu Xin-Ping2ORCID,Gong Xue-Qing2ORCID,Huang Weixin17ORCID

Affiliation:

1. Key Laboratory of Precise and Intelligent Chemistry, iChEM, Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China

2. Key Laboratory for Advanced Materials and Joint International Research Laboratory for Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Centre for Computational Chemistry and Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China

3. Hefei National Research Center for Physical Science at the Microscale, Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, University of Science and Technology of China, Hefei 230026, China

4. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China

5. School of Physical Science and Technology, Shanghai Tech University, Shanghai 201210, China

6. State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China

7. Dalian National Laboratory for Clean Energy, Chinese Academy of Sciences, Dalian 116023, China

Funder

Ministry of Education of the People's Republic of China

Ministry of Science and Technology of the People's Republic of China

Central University Basic Research Fund of China

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

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