How Do the Axial and Equatorial Ligands Modulate the Reactivity of a Metal-Bound Terminal Oxidant? An Answer from the Hypochlorite Adduct of Iron(III) Porphyrin

Author:

Yokota Sawako1,Suzuki Yuna1,Yanagisawa Sachiko2,Ogura Takashi2,Nozawa Shunsuke34,Hada Masahiko5ORCID,Fujii Hiroshi1ORCID

Affiliation:

1. Department of Chemistry, Biology, and Environmental Science, Graduate School of Humanities and Sciences, Nara Women’s University, Kitauoyanishi, Nara 630-8506, Japan

2. Graduate School of Science, University of Hyogo, Kouto, Kamigori, Ako, Hyogo 678-1297, Japan

3. Institute of Materials Structure Science, High Energy Accelerator Research Organization, 1-1 Oho, Tsukuba, Ibaraki 305-0801, Japan

4. Department of Materials Structure Science, School of High Energy Accelerator Science, The Graduate University for Advanced Studies, 1-1 Oho, Tsukuba, Ibaraki 305-0801, Japan

5. Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiosawa, Hachioji 192-0397, Japan

Funder

Core Research for Evolutional Science and Technology

Japan Society for the Promotion of Science

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

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